JEE Advanced 2013 Chemistry question

ChemistryElectrochemistryJEE Advanced 2013

The standard reduction potential data at 25 °C is given below. V; V V; V V; V V; V Match of the redox pair in List I with the values given in List II and select the correct answer using the code given below the lists : List I P. Q. R. S. List II 1. −0.36 V 2. −0.4 V 3. −0.04 V 4. −0.83 V

Answer: (D)

Solution

Combine half-reactions through ΔG° = −nFE°. P: : V → 3. Q: subtracting the acidic from the basic oxygen half-reaction gives with $E° = 0.40 - 1.23 =

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Question ID VK-026222