JEE Advanced 2025 Chemistry question
Molar volume () of a van der Waals gas can be calculated by expressing the van der Waals equation as a cubic equation with as the variable. The ratio (in mol dm⁻³) of the coefficient of to the coefficient of for a gas having van der Waals constants a = 6.0 dm⁶ atm mol⁻² and b = 0.060 dm³ mol⁻¹ at 300 K and 300 atm is . Use: Universal gas constant (R) = 0.082 dm³ atm mol⁻¹ K⁻¹
Answer: -7.1
Solution
becomes PV_m^3 - (Pb + RT)V_m^2 + aV_m - ab = 0. Ratio $=
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